His Excellency Archbishop Antonio Franco,
Titular Archbishop of Gallesium, from Italy,
is commonly regarded as the first Apostolic Nuncio in Ukraine.
He was appointed on 28 March 1992;
he presented his credentials on 19 August
and completed his mission in May 1999.
His successor was His Excellency Nikola Eterovic,
Titular Archbishop of Sisak, from Croatia,
was appointed on 30 May 1999.
He presented his credentials on 31 August 1999.
On 22 April 2004, His Excellency Archbishop Ivan Jurkovič, Titular Archbishop of Corbavia, from Slovenia, was appointed the Apostolic Nuncio in Ukraine. He presented his credentials on 16 June 2004.
On 21 May 2011, His Excellency Archbishop Thomas Edward Gullickson Titular Archbishop of Bomarzo was appointed the Apostolic Nuncio in Ukraine. He presented his credentials on 16 November 2011.